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The P-CaCl2 analysis for estimating plant available phosphorus in the soil

Content Author: SEGES Innovation

The Olsen-P test is used in Denmark as a standard analysis to determine available phosphorus (P) in the soil, and guidelines for P application are also based on it. However, in recent years, it has been found that this test is not always reliable for assessing P requirements, as several studies have shown yield increases in cereals that received P despite high expected P levels in the soil. The P-CaCl? test has been assessed through trials as more accurate than the Olsen-P test in certain areas of Denmark with naturally high levels of oxalate-extractable aluminum in the soil. Additionally, the method is expected to be more reliable on soils with low pH values. P-CaCl? is a soil test in which soil is shaken with the chemical calcium chloride (CaCl?), and the extracted P content is then measured. The same principle is used in the Olsen-P test with sodium bicarbonate, which also extracts the aluminium bound P. In both cases, the extracted amount is assumed to reflect the plant-available P in the soil. The method can be used as a supplementary test for soils where the Olsen-P test is not reliable, providing farmers with a more accurate assessment of the actual P requirement in the field.

Funded by the European Union and UK Research and Innovation (UKRI). Views and opinions expressed are however those of the author(s) only and do not necessarily reflect those of the European Union, European Commission or UKRI. Neither the European Union, European Commission nor UKRI can be held responsible for them.

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